期刊
ANALYTICA CHIMICA ACTA
卷 812, 期 -, 页码 222-227出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2014.01.014
关键词
Chemical warfare; Sulfur mustard; Porphyrazine; Monolayer based sensing; Optical monitoring
资金
- Department of Atomic Energy-Board of Research in Nuclear Sciences (DAE-BRNS [2010/20/37P/1/BRNS/1068-1]
- DAE-BRNS
- University Grants Commission
Covalently assembled monolayers (CAMs) of Mg-porphyrazine complex on glass and silicon substrates were fabricated and employed as Turn off sensor for ppm level detection and degradation of a sulfur mustard analogue: 2-chloroethyl ethyl sulfide (CEES). The detection process was read-out optically via an off-the-shelf UV/Vis spectrophotometer in transmission mode. Monolayer based sensor system was shown to be quite robust and stable, sufficiently accurate and reversible under given experimental conditions. Notably, the sensor system exhibited marked selectivity for CEES when exposed exclusively or in mix to different potent analytes. Moreover, action of KMn04 on monolayer-CEES complex lead to CEES degradation and resetting of the sensor to its native state for reuse. (C) 2014 Elsevier B.V. All rights reserved.
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