期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 16, 页码 6241-6246出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo070968e
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Here we report the synthesis and electrophosphorescence of a new deep-red phosphorescent Ir(III) complex with spatially embracing and thus solubilizing arylsilyl-substituted ligands, Ir(III) tris(2-(2'-benzo[b]thienyl)-5-(4'-triphenylsilylphenyl)pyridinato-N,C-3'). A poly(N-vinylcarbazole) (PVK) film doped with this Ir(III) complex exhibited excellent phase homogeneity and showed saturated red electrophosphorescence of 2.7% maximum external quantum efficiency, whose Commission Internationale de L'Eclairage coordinates were (0.69, 0.30).
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