期刊
ANALYTICA CHIMICA ACTA
卷 806, 期 -, 页码 152-164出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2013.11.006
关键词
Ionic liquids; Crown ether functionalized ionic liquids; Solid-phase microextraction; Sorbent coating; Sol-gel technology
资金
- National Natural Science Foundation of China [20807018, 21177047]
- Fundamental Research Funds for the Central Universities [2011PY138, 2011PY087]
- Wuhan Youth Science and Technology Chenguang Program [201271031378]
In this work, two novel crown ether functionalized ionic liquid (FIL)-based solid phase microextraction (SPME) fibers were prepared by sol-gel technology using the synthesized 1-(trimethoxysily)propyl 3-(6'-oxo-benzo-15-crown-5 hexyl) imidazolium bis(trifluoromethanesulphonyl)imide ([TMSP (Benzo15C5)HIM][N(SO2CF3)(2)]) and 1-allyl-3-(6'-oxo-benzo-15-crown-5 hexyl) imidazolium bis (trifluoromethanesulphonyl)imide ([A(Benzo15C5)HIM][N(SO2CF3)(2)]) as selective stationary phases. Owing to the introduction of trimethoxysilypropyl to the imidazole cation, the [TMSP(Benzo15C5) HIM][N(SO2CF3)(2)] could be chemically bonded to the formed sol-gel silica substrate through the hydrolysis and polycondensation reaction. Similarly, the [A(Benzo15C5)HIM][N(SO2CF3)(2)] was able to participate in the formation of the organic-inorganic copolymer coatings through the free radical crosslinking reaction. These two fibers were determined to have bubble-like surface characteristics analogous to a previously prepared [A(Benzo15C5)HIM][PF6]-based fiber. Their thermal stabilities were much higher than that of the [A(Benzo15C5)HIM][PF6]-based coating. They were capable of withstanding temperatures as high as 400 degrees C without evident loss of the crown ether FILs. They also had strong solvent, acid and alkali resistance, good coating preparation reproducibility and high selectivity for medium polar to polar compounds. The high selectivity of these two fibers could be attributed to the strong ion-dipole, hydrogen bonding and pi-pi interactions provided by the synergetic effect of ILs and benzo-15-crown-5 functionalities. Moreover, the selectivity of these two fibers was rather different although the structures of these two crown ether FILs were very similar. This is maybe because the relative contents of the crown ether FILs chemically bonded to the organic-inorganic copolymer coatings were quite different when prepared by different sol-gel reaction approaches. (C) 2013 Elsevier B.V. All rights reserved.
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