期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 31, 页码 9592-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja073457i
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Catalyzed movement of alkene double bonds up to 30 positions has been accomplished using a catalyst featuring a cationic CpRu fragment and bifunctional imidazolylphosphine. The basic nitrogen of the latter is thought to deprotonate coordinated alkene intermediates reversibly, facilitating isomerization between terminal and (E)-alkenes and accelerating conversions by factors of up to 1 x 10(4).
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