期刊
TETRAHEDRON-ASYMMETRY
卷 18, 期 15, 页码 1868-1876出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2007.07.026
关键词
-
The chirality of micellar aggregates formed by surfactants derived from L-proline was investigated by using two chiral biphenylic derivatives as probes of chirality. The investigation carried out by H-1 NMR, circular dichroism, and HPLC on chiral phase demonstrates that chiral recognition may occur in sites of the aggregates far from the head-group stereogenic centers and it is due to interaction with a whole region of the aggregate rather than with a single monomer in the aggregate. Subtle changes of the structure of the monomer influence the aggregation properties of the surfactants and its expression of chirality. (C) 2007 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据