期刊
TETRAHEDRON
卷 63, 期 33, 页码 7874-7878出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.05.089
关键词
diarylheptanoid; tetrahydropyran; diospongin A; Prins cyclization
A straightforward synthesis of (+/-)-diospongin A starting from benzaldehyde is described. A Prins cyclization reaction to control the relative configuration of the three stereogenic centers and a Mitsunobu inversion represent the key steps of the approach. (C) 2007 Elsevier Ltd. All rights reserved.
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