期刊
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
卷 17, 期 16, 页码 4650-4653出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.bmcl.2007.05.073
关键词
ruthenium porphyrin; sulfide; sulfoxide; dioxygen
Highly efficient selective oxidation of sulfides to sulfoxides by molecular oxygen catalyzed by ruthenium (III) meso-tetraphenylporphyrin chloride (Ru(TPP)Cl) with isobutyraldehyde as oxygen acceptor has been reported. In large-scale experiment of thioanisole oxidation, the isolated yield of sulfoxide of 92% was obtained and the turnover number reached up to 92,000. (c) 2007 Elsevier Ltd. All rights reserved.
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