4.8 Article

Magnetically separable Pd catalyst for highly selective epoxide hydrogenolysis under mild conditions

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ORGANIC LETTERS
卷 9, 期 17, 页码 3417-3419

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AMER CHEMICAL SOC
DOI: 10.1021/ol701456w

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A magnetically separable palladium catalyst was synthesized simply through a sol-gel process incorporating palladium nanoparticles and superparamagnetic iron oxide nanoparticles in aluminum oxyhydroxide matrix, which is highly active and selective for epoxide hydrogenolysis at room temperature under 1 atm H-2. The catalyst was recycled for 25 times without loss of the activity.

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