期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 17, 页码 6513-6520出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo070750s
关键词
-
资金
- NIGMS NIH HHS [R01 GM062160-06, GM 62160, R01 GM062160] Funding Source: Medline
A synthesis of the pentenyl glycoside of the tetrasaccharide side chain from the major glycoprotein of Bacillus anthracis by a [3 + 1] approach is described. The construction of the 1,2-trans-glycosidic linkage in the terminal anthrose moiety was achieved through the application of known alpha-nitrilium ion-mediated beta-selective glycosylation methodology. An iterative glycosylation strategy was used for the assembly of the trirhamnan building block. A new route to the anthrose saccharide was developed from D-galactose.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据