期刊
ANALYTICA CHIMICA ACTA
卷 729, 期 -, 页码 7-20出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2012.03.060
关键词
Electroanalysis of phosphate; Review; Potentiometry; Amperometry; Bioelectroanalytical methods
资金
- School of Chemical and Mathematical sciences, Murdoch university, Murdoch, Australia
Determination of inorganic phosphate is of very high importance in environmental and health care applications. Hence knowledge of suitable analytical techniques available for phosphate sensing for different applications becomes essential. Electrochemical methods for determining inorganic phosphate have several advantages over other common techniques, including detection selectivity, stability and relative environmental insensitivity of electroactive labels. The different electrochemical sensing strategies adopted for the determination of phosphate using selective ionophores are discussed in this review. The various sensing strategies are classified based on the electrochemical detection techniques used viz., potentiometry, voltammetry, amperometry, unconventional electrochemical methods etc., The enzymatic sensing of phosphate coupled with electrochemical detection is also included. Various electroanalytical methods available in the literature are assessed for their merits in terms of selectivity, simplicity, miniaturisation, adaptability and suitability for field measurements. (C) 2012 Elsevier B.V. All rights reserved.
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