期刊
ANALYTICA CHIMICA ACTA
卷 708, 期 1-2, 页码 111-115出版社
ELSEVIER
DOI: 10.1016/j.aca.2011.09.034
关键词
Luminescent; Copper ion; Iron ion; Terbium
资金
- start fund of Guangdong talents [C10208]
A novel green emissive terbium inorganic-polymeric hybrid particle was designed and this material could detect cations in water. Polyvinyl alcohol as an amphiphilic surfactant rendered the powders dispersible in water with regular round shape (10-20 mu m). Interestingly, we noticed that not only Cu2+ (detection limit 10(-4) M) but also Fe3+ (detection limit 10(-4) M) can give rise to emission quenching to this target material in comparison with K+, Na+, Fe2+, Mn2+, Pd2+, Cd2+ and Co2+ (10(-3) mol L-1). We regarded that the coordination interactions between ligand and metal ions resulted in these quenching processes. Additionally, it was found that the sensing material can be repeatedly used at least 5 cycles. More importantly, this novel material demonstrated higher thermal-stability in aqueous media than pure silica hybrid material. (C) 2011 Elsevier B.V. All rights reserved.
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