期刊
ANALYTICA CHIMICA ACTA
卷 688, 期 2, 页码 146-155出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2010.12.033
关键词
Graphene nanosheets; Conducting agent; Cycle performance; Rate performance; AC impedance
资金
- Foundation of Excellent Doctoral Dissertation of Beijing City [YB20081001001]
The structure and electronic properties of graphene nanosheet (GNS) render it a promising conducting agent in a lithium-ion battery. A graphite electrode loaded with GNS exhibits superior electrochemical properties including higher rate performance, increased specific capacity and better cycle performance compared with that obtained by adding the traditional conducting agent-acetylene black. The high-quality sp(2) carbon lattice, quasi-two-dimensional crystal structure and high aspect ratio of GNS provide the basis for a continuous conducting network to counter the decrease in electrode conductivity with increasing number of cycles, and guarantee efficient and fast electronic transport throughout the anode. Effects of GNS loading content on the electrochemical properties of graphite electrode are investigated and results indicate that the amount of conductive additives needed is decreased by using GNS. The kinetics and mechanism of lithium-storage for a GNS-loaded electrode are explored using a series of electrochemical testing techniques. (C) 2011 Elsevier B.V. All rights reserved.
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