期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 208, 期 16, 页码 1823-1831出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200700078
关键词
block copolymers; honeycomb structure; superhydrophobic surface; surfaces
The self-assembly of PVPh-b-PS in different solvents was studied. Upon replacing toluene by THF as the solvent, the morphology of the resulting aggregates change from core-shell spheres, rod-like micelles and vesicles to onion-like aggregates. With increasing block copolymer concentration, morphologies such as honeycomb-like films, surfaces of aggregated large porous spheres, or pincushion-like spheres with protruding tubular vesicle aggregates are observed. These surface-patterned films show significantly enhanced hydrophobicity. The results suggest that a superhydrophobic . behavior can be achieved, with a maximum contact angle of 158 degrees, by using the pincushion-like micellar structure.
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