期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 33, 页码 10108-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja074158w
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Solvent water (Gutmann acceptor number, AN = 55) accelerates the rate of reaction of Ru(terpy)(bpy)H+ with CO2 by more than 4 orders of magnitude compared to acetonitrile (AN 18.9) (as reported in Inorg. Chim. Acta 2000, 299, 155). Water also promotes the related reductions of carbon monoxide to formaldehyde and of formaldehyde to methanol by the ruthenium(II) hydride complex.
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