期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 147, 期 3, 页码 964-970出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2007.01.127
关键词
electrochemical catalytic oxidation; toluene; methanol; solid superacid
The electrochemical catalytic reaction of toluene with methanol, assisted with a pair of porous graphite plate electrodes, catalyzed by solid superacid of cobalt modification catalyst with chemical conversion higher than 81%, was described and investigated by UV-vis spectrum, scan electron microscopy (SEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and gas chromatography-mass spectrometry (GC-MS). A possible free radical reaction mechanism was proposed. It may be concluded that a simply and feasible electrochemical catalytic coupling oxidation reaction at room temperature and air pressure may be possible. (C) 2007 Elsevier B.V. All rights reserved.
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