期刊
ANALYTICA CHIMICA ACTA
卷 670, 期 1-2, 页码 92-97出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2010.04.060
关键词
Short wave near infrared; Diesel fuel; Cetane index; Partial least squares; Instrumentation
资金
- FAPESP [05/04456-2]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [05/04456-2] Funding Source: FAPESP
A low cost absorption spectrophotometer for the short wave near infrared spectral region (850-1050 nm) is described. The spectrophotometer is basically composed of a conventional dichroic lamp, a long-pass filter, a sample cell and a Czerny-Turner type polychromator coupled to a 1024 pixel non-cooled photodiode array. A preliminary evaluation of the spectrophotometer showed good repeatability of the first derivative of the spectra at a constant room temperature and the possibility of assigning some spectral regions to different C-H stretching third overtones. Finally, the spectrophotometer was successfully applied for the analysis of diesel samples and the determination of some of their quality parameters using partial least squares calibration models. The values found for the root mean square error of prediction using external validation were 0.5 for the cetane index and from 2.5 to 5.0 degrees C for the temperatures achieved during distillation when obtaining 10, 50, 85, and 90% (v/v) of the distilled sample, respectively. (C) 2010 Elsevier B.V. All rights reserved.
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