期刊
ANALYTICA CHIMICA ACTA
卷 667, 期 1-2, 页码 43-48出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2010.04.016
关键词
Cold vapor; Atomic fluorescence spectrometry; Mercury; Microwave digestion; Rice
资金
- CNPq
- CAPES
- Ministerio de Ciencia e Innovacion [AGL2007-64567]
- Direccion General de Salud Publica de la Generalitat Valenciana [Ref-A-05/09]
A cold vapor atomic fluorescence spectrometry method (CV-AFS) has been developed for the determination of Hg in rice samples at a few ng g(-1) concentration level. The method is based on the previous digestion of samples in a microwave oven with HNO3 and H2O2 followed by dilution with water containing KBr/KBrO3 and hydroxylamine and reduction with SnCl2 in HCl using external calibration. The matrix interferences and the effect of nitrogen oxide vapors have been evaluated and the method validated using a certified reference material. The limit of detection of the method was 0.9 ng g(-1) with a recovery percentage of 95 +/- 4% at an added concentration of 5 ng g(-1). The concentration level of Hg found in 24 natural rice samples from different origin ranged between 1.3 and 7.8 ng g(-1). (C) 2010 Elsevier B.V. All rights reserved.
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