期刊
ANALYTICA CHIMICA ACTA
卷 666, 期 1-2, 页码 55-61出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2010.03.039
关键词
Sequential injection analysis; Dual-valve system; Liquid-liquid extraction; Picric acid
资金
- International Visegrad Fund
- Faculty of Science of Pavol Jozef Safarik University in Kosice [24/2009/CH]
- Ministry of Education of the Czech Republic [MSM 0021620822]
A novel dual-valve sequential injection system (DV-SIA) for online liquid-liquid extraction which resolves the main problems of LLE utilization in SIA has been designed. The main idea behind this new design was to construct an SIA system by connecting two independent units, one for aqueous-organic mixture flow and the second specifically for organic phase flow. As a result, the DV-SIA manifold consists of an Extraction unit and a Detection unit. Processing a mixture of aqueous-organic phase in the Extraction unit and a separated organic phase in the Detection unit solves the problems associated with the change of phases having different affinities to the walls of the Teflon tubing used in the SI-system. The developed manifold is a simple, user-friendly and universal system built entirely from commercially available components. The system can be used fora variety of samples and organic solvents and is simple enough to be easily handled by operators less familiar with flow systems. The efficiency of the DV-SIA system is demonstrated by the extraction of picric acid in the form of an ion associate with 2[2-(4-metoxy-fenylamino)-vinyl]-1,3,3-trimetyl-3H-indolium reagent, with subsequent spectrophotometric detection. The suggested DV-SIA concept can be expected to stimulate new experiments in analytical laboratories and can be applied to the elaboration of procedures for the determination of other compounds extractable by organic solvents. It could thus form a basis for the design of simple, single-purpose commercial instruments used in LLE procedures. (C) 2010 Elsevier B.V. All rights reserved.
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