4.7 Article

Dielectric spectroscopy in benzophenone:: The β relaxation and its relation to the mode-coupling Cole-Cole peak

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PHYSICAL REVIEW E
卷 76, 期 3, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.76.030502

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We report a thorough characterization of the glassy dynamics of benzophenone by broadband dielectric spectroscopy. We detect a well-pronounced beta relaxation peak developing into an excess wing with increasing temperature. A previous analysis of results from Optical-Kerr-effect measurements of this material within the mode-coupling theory revealed a high-frequency Cole-Cole peak. We address the question if this phenomenon also may explain the Johari-Goldstein beta relaxation, a so-far unexplained spectral feature inherent to glass-forming matter, mainly observed in dielectric spectra. Our results demonstrate that according to the present status of theory, both spectral features seem not to be directly related.

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