A novel separation/preconcentration system based on solidification of floating organic drop microextraction for determination of lead by graphite furnace atomic absorption spectrometry

Solidified floating organic drop microextraction (SFODME) was successfully used as a sample preparation method for graphite furnace atomic absorption spectrometry (GFAAS). 20 mu L of 1-undecanol containing dithizone as the chelating agent (2 x 10(-4) mol L-1) was transferred to the water samples containing lead ions, and the solution was stirred for the prescribed time. The sample vial was cooled in an ice bath for 5 min. The solidified extract was transferred into a conical vial where it melted immediately, and then 10 mu L of it was analyzed by GFAAS. Factors that influence the extraction and complex formation, such as pH, concentration of dithizone, extraction time, sample volume, and ionic strength were optimized. Under the optimized conditions, a good relative standard deviation of +/- 5.4% at 10 ng L-1 and detection limit of 0.9ng L-1 were obtained. The procedure was applied to tap water, well water, river water and sea water, and accuracy was assessed through the analysis of certified reference water or recovery experiments. (C) 2008 Elsevier B.V. All rights reserved.