期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 26, 页码 4197-4206出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200700424
关键词
copper(I) and copper(II) complexes; catalysis; oxidation; luminescence; bioinorganic chemistry
New pyrazole-based ligands have been designed, and the catalytic performances of their copper(II) complexes for the [copper/TEMPO]-mediated oxidation of benzyl alcohol to benzaldehyde have been examined. The pyridine-pyrazole ligands give efficient catalysts, while the use of naphthol-pyrazole ligands results in inactive catalytic systems. Singlecrystals of four Cu coordination compounds obtained from pyridine-pyrazole ligands and a free ligand have been isolated and were characterized by X-ray diffraction. Thus, the solid-state structures of three copper(II) complexes are described, together with a copper(I) coordination chain, exhibiting luminescent properties. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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