期刊
ANALYST
卷 136, 期 10, 页码 2040-2043出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1an15050b
关键词
-
资金
- National Basic Research Program of China [2011CB935800]
In this Communication, we report water-soluble nano-C-60 in the first use as an effective fluorescent sensing platform for the highly sensitive and selective detection of Ag+. The general concept used in this approach is based on a fluorescently labeled single-stranded DNA (ssDNA) probe that adsorbs on nano-C-60, leading to substantial dye fluorescence quenching; however, in the presence of Ag+, C-Ag+-C coordination induces the probe to fold into a hairpin structure, which does not adsorb on nano-C-60 and thus retains the dye fluorescence. This sensing system exhibits a detection limit as low as 1 nM and has a high selectivity against other metal ions. Finally and most importantly, we demonstrate its performance in real sample analysis.
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