期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 274, 期 1-2, 页码 58-64出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2007.04.031
关键词
alumina; oxidation; cyclohexene; Schiff-base
New square-planar manganese(II), copper(II), nicke(II) and cobalt(II) complexes of a tetradentate Schiff-base ligand bis(2-mercaptoanil)benzil, H-2[mabenzil] have been prepared and characterized by elemental analyses, IR, UV-vis, conductometric and magnetic measurements. The results suggest that the symmetrical Schiff-base is a bivalent anion with tetradentate N2S2 donors derived from the thiopbenole groups and azomethine nitrogen. The formulae was found to be [M(mabenzil)] for the 1:1 non-electrolytic complexes. Alumina-supported metal complexes (ASMC; [M(mabenzil)/Al2O3]) catalyze the oxidation of cyclohexene with tert-buthylhydroperoxide (TBHP) and H2O2. (c) 2007 Elsevier B.V. All rights reserved.
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