期刊
ADVANCED MATERIALS
卷 19, 期 17, 页码 2351-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200602348
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- National Research Foundation of Korea [R0A-2004-000-10367-0, 과C6B1913, R0A-2007-000-10029-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A novel poly(vinyl)silazane-block-polystyrene diblock copolymer is successfully synthesized by living free-radical polymerization via a reversible addition fragmentation chain transfer (RAFT) route (see figure). The obtained diblock copolymer, having an inorganic volume fraction of 0.69, leads to phase-separation at the nanoscale to form an ordered nanostructure, which is converted to well-ordered mesoporous SiCN ceramic after heating at 800 degrees C and maintained up to 1400 degrees C.
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