期刊
TETRAHEDRON LETTERS
卷 48, 期 37, 页码 6463-6465出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.07.068
关键词
botcinolides; botcinic acid; dihydroxylation; aldol reaction; sharpless epoxidation
Synthesis of the highly substituted polyoxygenated tetrahydropyran ring of botcinic acid, the revised structure of botcinolide is achieved using, as key steps, a highly stereoselective aldol reaction of the titanium enolate from a lactate-derived chiral ketone and a stereoselective dihydroxylation. (c) 2007 Elsevier Ltd. All rights reserved.
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