期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 275, 期 1-2, 页码 174-182出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2007.05.027
关键词
amorphous alloy; Fe-P; dehydrogenation; ethanol
Fe-P ultrafine amorphous alloy particles have been synthesized by chemical reduction of various iron precursors such as FeC124H'0, FeCl3-6H(2)O and Fe(OAc)(2) under different preparation mediums, viz., H2O, ethanol/H2O, and isopropyl alcohol/H2O. The synthesized materials were characterized by X-ray diffraction, inductively coupled plasma-atomic emission spectroscopy, N, sorption, transmission electron microscopy, X-ray photoelectron spectroscopy, and electron diffraction. The results indicated the existence of amorphous nature of Fe-P materials even when the treatment temperature was up to 400 degrees C. The structure, morphology, and composition of Fe-P nanoalloys have been significantly influenced by the iron precursor and the type of solvent. Dehydrogenation of ethanol has been carried out in order to evaluate the catalytic properties of the Fe-P narroalloys and related to the surface properties of Fe-P nanoalloys. Sample Fe-89.P-1(10.9) prepared with FeCl3-6H(2)O in isopropyl alcohOl/H2O solvent showed the highest activity owing to its high surface area and high turnover frequency. (c) 2007 Elsevier B.V. All rights reserved.
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