An IR study of thermally stable V2O5-WO3-TiO2SCR catalysts modified with silica and rare-earths (Ce, Tb, Er)

The catalytic activity of silica-free and silica-modified rare earth (Ce, Tb, Er) containing V2O5-WO3 -TiO2 catalysts in the selective catalytic reduction of NO by ammonia has been investigated as a function of ageing temperatures. The adsorption of ammonia on the catalysts and the behavior of their surface hydroxy groups and of bulk vibrations has also been studied by IR spectroscopy. Rare earths slightly decrease the catalytic activity of catalysts in a fresh state, and this has been attributed to the perturbation, observed by IR, of the vanadyl groups with a likely lowering of their Lewis acidity. However, rare earths (in particular Tb and Er) increase strongly the catalytic activity of catalysts after ageing. Silica only does not seem to have a positive effect on thermal stability and activity when vanadium is present. It has been concluded that rare earths strongly increase the thermal resistance of the catalysts and inhibit rutilization and surface area loss because they do not penetrate the anatase bulk while tend to cover the external surface. In addition the negative action of free vanadium on phase stability is decreased due to formation of rare earth vanadates. (c) 2007 Elsevier B.V. All rights reserved.