期刊
EUROPEAN POLYMER JOURNAL
卷 43, 期 10, 页码 4486-4492出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2007.04.014
关键词
atom transfer radical polymerization (ATRP); microwave irradiation (MI); azo side-chain; NLO
Micro-wave irradiation (MI) was applied to the atom transfer radical polymerization (ATRP) of azo-containing acrylates. The polymerization was greatly promoted and the reaction time was shortened from several days to about I h. The polymerization was well-controlled within an incipient period but it was influenced by hyperthermia effect after a certain time. The functional polymers obtained under MI process have good third-order nonlinear optical (NLO) properties as those of polymers obtained under CH process. (C) 2007 Elsevier Ltd. All rights reserved.
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