期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 7, 期 10, 页码 3365-3372出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2007.836
关键词
multiwall carbon nanotubes; gold nanoparticles; glucose; sensor
A modified electrode based on gold nanoparticles decorated multiwall carbon nanotubes (MWNTs), MWNT-Au-nano-ME is fabricated. MWNTs are functionalized with 4-aminothiophenol and coated over the glassy carbon electrode. Further, Au nanoparticles are deposited into MWNTs coated GC electrode by electrochemical reduction of HAuCl4- Field emission transmission electron microscope (FETEM) image shows the formation of similar to 5 nm sized Au degrees nanoparticles without any agglomeration on the MWNTs surface. Further, the presence of Au degrees nanoparticles is confirmed through X-ray photoelectron spectroscopic (XPS) studies. The electrocatalytic activity of the MWNT-Au-nano-ME towards the detection of glucose is investigated. MWNT-Au-nano-ME shows enhanced current response than pristine MWNT-ME over the entire (+0.05 to +0.80 V) potential range. The modified electrode shows linear response to current with the concentration of glucose between 1 and 20 mM. Larger current responses to glucose oxidation are witnessed at +0.60 V than at +0.05 V. However, a large interference signal, reflecting the accelerated oxidation of electroactive interference is observed at +0.60 V No overlapping signal from the interferents such as ascorbic acid, acetaminophen, and dopamine are observed at the MWNT-Au-nano-ME at +0.05 V. Further, the MWNT-Au-nano-ME shows high resistance to the toxictiy of chloride ions.
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