期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 90, 期 1, 页码 81-84出版社
SPRINGER
DOI: 10.1007/s10973-007-8479-8
关键词
Faraday; mechanochemistry; self-sustaining reactions
Faraday induced the mechanochemical reduction of AgCl with Zn, Sn, Fe and Cu in 1820, using trituration in a mortar. This experiment is revisited, employing a mortar-and-pestle and a ball mill as mechanochemical reactors. The reaction kinetics depends both on the thermochemical properties and the hardness of the reactants. When using Zn as the reducing agent, Faraday likely observed a mechanically induced self-sustaining process (MSR), or at least he came very close to doing so.
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