期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 41, 页码 12368-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja074366o
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The covalent modification of the metal-organic framework IRMOF-3 has been achieved using acetic anhydride. Mass spectrometry and H-1 NMR evidence shows that the free amine groups in IRMOF-3 are converted to amides in high yields. Control experiments and X-ray diffraction studies suggest that this reaction occurs on the intact framework with preservation of crystallinity. This finding opens up new possibilities for the preparation of novel MOFs using a postsynthetic modification strategy.
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