期刊
TETRAHEDRON-ASYMMETRY
卷 18, 期 21, 页码 2499-2502出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2007.10.012
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A titanium complex derived from 3-(3,5-diphenylphenyl)-H-8-BINOL exhibits high catalytic activity and enantioselectivity in the alkylation of aldehydes. Enantioselectivities comparable to or higher than 20 mol % of the parent H-8-BINOL are obtained with 2 mol %-catalyst loadings. The reaction can be carried out without rigorous exclusion of water. (c) 2007 Elsevier Ltd. All rights reserved.
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