期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 43, 页码 12950-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja076539f
关键词
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Dicationic SEGPHOS-Pd complex-catalyzed ketoester-ene reaction with silyl enol ether can be achieved to produce an ene product with a quaternary carbon center in high yield and enantioselectivity. Even lower catalyst loading (up to 0.01 mol%) can be performed without a significant decrease in yield and enantioselectivity; this will open doors to industrial applications of chiral Lewis acid catalysis.
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