期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 33, 页码 5177-5181出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200700723
关键词
boron; charge transfer; polymers; self-assembly
The three-component reaction of aryl boronic acids with 1,2,4,5-tetrahydroxybenzene and 1,2-bis (4-pyridyl) ethylene or 4,4'-bipyridine leads to the formation of dark-purple boronate ester polymers. Crystallographic analyses show that the polymer strands have a zig-zag geometry, and the bis(dioxaborole) units are connected by dipyridyl linkers through dative B-N interactions. Upon dissolution of the polymers in hot chloroform, most of the B-N connections are broken, which indicates that polymer formation is a reversible process. A computational study provides evidence that the strong color of the polymers is due to efficient intrastrand charge-transfer excitations from the tetraoxobenzene to the dipyridyl linker. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
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