期刊
CURRENT ORGANIC SYNTHESIS
卷 4, 期 4, 页码 390-412出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017907782408770
关键词
azamacrocycles; molecular recognition; transition metal complexes; cyclam; cyclen; TACN
Azamacrocycles show high affinity for the complexation of a wide range of transition metals. By additional reversibly coordinated ligands, these metal complexes have shown to be interesting tools for molecular recognition, especially for biological systems. Herein, the role of metal complexes of 1,4,8,11-tetraaza-cyclotetradecane ([14]aneN(4) or cyclam), 1,4,7,10-tetraaza-eyelododecane ([12]aneN4 or cyclen), 1,5,9-triaza-cyclododecane ([12]aneN(3)), 1,4,7-triaza-cyclo non a ne ([9]aneN(3) or TACN) is reviewed.
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