期刊
PURE AND APPLIED CHEMISTRY
卷 79, 期 11, 页码 1917-1927出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200779111917
关键词
photocatalysts; water splitting; solar light; hydrogen; metal oxides; metal sulfides
Photocatalytic water splitting is a challenging reaction because it is an ultimate solution to energy and environmental issues. Recently, many new powdered photocatalysts for water splitting have been developed. For example, a NiO (0.2 wt %)/NaTaO3:La (2 %) photocatalyst with a 4.1-eV band gap showed high activity for water splitting into H-2 and O-2 with an apparent quantum yield of 56 % at 270 nm. Overall water splitting under visible light irradiation has been achieved by construction of a Z-scheme photocatalysis system employing visible-light-driven photocatalysts, Ru/SrTiO3:Rh and BiVO4 for H-2 and O-2 evolution, and an Fe3+/Fe2+ redox couple as an electron relay. Moreover, highly efficient sulfide photocatalysts for solar hydrogen production in the presence of electron donors were developed by making solid solutions of ZnS with AgInS2 and CuInS2 of narrow band gap semiconductors. Thus, the database of powdered photocatalysts for water splitting has become plentiful.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据