期刊
MENDELEEV COMMUNICATIONS
卷 17, 期 6, 页码 337-339出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2007.11.013
关键词
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Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazines have been prepared as bis(pyridine) adducts [PY2Fe(XN2)PAPh(6)] (X = S, Se) from the corresponding Mg-II complexes obtained by template co-cyclotetramerization of diphenylfumarodinitrile with 1,2,5-thia/selenadiazolo-3,4-dicarbonitriles, and the unusual direct replacement of Se by S in the reaction of [Py2Fe(SeN2)PAPh(6)] with H2S has been observed.
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