期刊
ADVANCED MATERIALS
卷 19, 期 21, 页码 3594-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200700014
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The rigid backbone of the poly(3-butylthiophene) molecule adopts a perpendicular orientation with respect to the substrate by using a solvent-vapor treatment (see figure). Small and closely contacting spherulites instead of conventional whisker-like crystals are achieved. This could be utilized to improve charge-carrier mobility particularly in the direction normal to the film plane by designing and constructing thick crystalline domains in the functional layer.
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