期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 44, 页码 13404-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja076179w
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资金
- NIGMS NIH HHS [GM 43214, P01 GM 69721] Funding Source: Medline
Highly enantioenriched indolizinone and quinolizinone products are obtained in the thiourea-catalyzed cyclization of tryptamine-derived hydroxylactams. Substituent and counterion effect studies point to a novel mechanism of catalysis involving rate-limiting anion abstraction and binding by the thiourea.
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