期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 111, 期 45, 页码 11584-11588出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp075526l
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The photochemical redox reaction kinetics of [M(III)(C2O4)(3)](3-) [M = Co, Fe] complexes have been reexamined and studied by time-resolved spectroscopy. The redox mechanisms of the two systems, Co and Fe, were found to be similar to each other, and solvated electrons were observed immediately after 266/267 nm photoexcitation. A reaction mechanism is proposed that involves photoelectron detachment as a primary process. The charge-transfer bands for both complexes, which had been attributed to ligand to metal charge-transfer (LMCT) transitions previously, are reassigned to charge transfer to solvent (CTTS) transitions.
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