期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 111, 期 45, 页码 17008-17014出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp076923z
关键词
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Electrodes modified with random arrays of nanoparticles and/or microparticles find significant application in electroanalysis. Theory is developed for the diffusional current at nanoparticle-modified electrodes via the diffusion domain approach which is used to model the electrode surface as a randomly distributed assembly of spherical particles. Experiments are reported for the electrocatalytic reduction of protons at a palladium particle modified electrode and shown to behave as predicted theoretically.
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