期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 277, 期 1-2, 页码 102-106出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2007.07.021
关键词
block copolymers; microspheres; micelles; palladium; raspberry-like colloid; Suzuki reaction
A strategy to facilitate reuse of palladium catalyst stabilized by block copolymer micelles is proposed. Following this strategy, the polystyrene-b-poly(4-vinyl pyridine) micelles were firstly anchored on the surface of polystyrene-co-poly(methyl acrylic acid) core-shell microspheres to form raspberry-like colloid. Then the raspberry-like colloid was used as scaffold to support colloidal palladium catalyst. The resultant raspberry-like colloid supported palladium catalyst, which showed similar activity to the catalyst stabilized by block copolymer micelles and much improved recoverability, was demonstrated to be a good alternative for Suzuki reaction either performed in water or in DMF/water. (C) 2007 Elsevier B.V. All rights reserved.
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