期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 46, 页码 14190-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0760426
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资金
- NIGMS NIH HHS [R37 GM047365, R37 GM047365-17, GM47365, R01 GM047365, R01 GM047365-15, R01 GM047365-16] Funding Source: Medline
A series of copper(I)-alpha-ketocarboxylate complexes have been prepared and shown to exhibit variable coordination modes of the alpha-ketocarboxylate ligand. Reaction with O-2 induces decarboxylation of this ligand, and the derived copper-oxygen intermediate(s) has been intercepted, resulting in hydroxylation of an arene substituent on the supporting N-donor ligand. Theoretical calculations have provided intriguing mechanistic notions for the process, notably implicating hydroxylation pathways that involve novel [Cu-I-OOC(O) R] and [Cu-II-O-center dot <-> CUIII=O2-](+) species.
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