期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 46, 页码 14172-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja076659n
关键词
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We have found that the addition of base has a significant effect on palladium-catalyzed allylic amination. The long-standing problem of controlling the branched-to-linear ratio has been solved. In the presence of DBU and inexpensive, readily available ligands, palladium-catalyzed allylation proceeds under kinetic control, leading to high branched selectivity. Given the widespread utility of palladium-catalyzed allylic amination, we expect that these findings will be relevant in many areas ranging from asymmetric catalysis to target-oriented synthesis.
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