期刊
SUPRAMOLECULAR CHEMISTRY
卷 19, 期 8, 页码 579-585出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270701432460
关键词
2,2'-bipyridyl (bpy); fluorinated thiolate complexes; platinum complexes; crystal engineering; pi-pi stacking
A series of platinum thiolate complexes of the type [Pt(bpy)(SRF)2] (bpy = 2,2'-bipyridyl and SRF = -SC6F5 (1), -SC6F4-4-H (2)) have been synthesized in good yields by metathetical reactions of [Pt(bpy)Cl-2] with [Pb(SRF)2], (SRF = SC6F5, -SC6F4-4-H) and their crystal structures determined. The effect of the different thiolates in the structural properties of the complexes both in the solid state and in solution have been analyzed. The analyses in solid state suggests that the difference in pi-pi interactions among the aromatic rings may cause the different arrangements of the molecules in the crystal structures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据