期刊
ACCOUNTS OF CHEMICAL RESEARCH
卷 40, 期 12, 页码 1300-1308出版社
AMER CHEMICAL SOC
DOI: 10.1021/ar700134q
关键词
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Recent development of conceptually new chiral bifunctional transition metal based catalysts for asymmetric reductive transformations is described. The chiral bifunctional molecular catalyst promoted reduction is now realized to be a powerful tool to access chiral compounds in organic synthetic procedures in both academia and industry. Based on structural investigation of the actual catalyst and its intermediates and a deep understanding of the reaction mechanism, this asymmetric reduction system can be widely used to produce valuable chiral alcohols ani is now is applicable to commercial scale production.
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