期刊
DIAMOND AND RELATED MATERIALS
卷 16, 期 12, 页码 2035-2038出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2007.06.003
关键词
ultrananocrystalline diamonds; magnetic properties; SQUID; electron paramagnetic resonance
Electron paramagnetic resonance (EPR) and magnetic susceptibility measurements were done on nanodiamond samples fabricated-by the detonation method and purified by acids. Comprehensive acid treatment leads to the reduction of EPR signals of magnetic impurities and revealing two weak and narrow EPR lines with g, =4.26, Delta H-pp= 2.9 mT and g(2) =4.00, Delta H-pp = 1.4 mT at T=4 K, separated by the distance of 10.4 mT. The origin of this new doublet EPR signal observed in the well purified sample is discussed. The magnetic susceptibility behavior and doublet EPR signal (g similar to 4) suggest the weak antiferromagnetically exchange coupling of S = 1/2 paramagnetic defects as well as the presence of isolated dimers with S=1. (C) 2007 Elsevier B.V. All rights reserved.
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