期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 25, 页码 9630-9634出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo7014455
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[GRAPHICS] The carbonylative opening of terminal epoxides under mild conditions has been developed using CO2-(CO)(8) as the catalyst. Under I atm of carbon monoxide and at room temperature in methanol, propylene oxide is converted to methyl 3-hydroxybutanoate in up to 89% yield. This transformation is general for many terminal epoxides bearing alkyl, alkenyl, aryl, alkoxy, chloromethyl, phthalimido, and acetal functional groups. The opening takes place without epimerization at the secondary stereocenter.
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