期刊
TETRAHEDRON
卷 63, 期 50, 页码 12429-12436出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.09.028
关键词
1,3,4-oxadiazole; liquid crystals; columnar mesophases; fluorescence
A new series of liquid-crystalline bi-1,3,4-oxadiazole derivatives (2,2'-bis(3,4,5-trialkoxyphenyl)-bi-1,3,4-oxadiazole, BOXD-T-n, n=3, 4, 5, 6, 7, 8, 10, 14) were designed and synthesized. They have been confirmed to give rise to columnar mesophases. The columnar mesophases for BOXD-Tn (n=5, 6, 7, 8, 10) could be supercooled to -20 degrees C on the cooling runs. A room temperature Col(ho) phase was obtained for BOXD-T14. All BOXD-Tn exhibit good fluorescence properties either in cyclohexane or in solid state. (c) 2007 Elsevier Ltd. All rights reserved.
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