期刊
INORGANIC CHEMISTRY
卷 46, 期 25, 页码 10449-10451出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic701628f
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While typically structures from linear diphosphonate ligands form dense phases, we report that with the functionalized ligand 1,4-dihydroxy-2,5-benzenediphosphonate (DHBP) and Zn2+ a microporous network is formed. {[Zn(DHBP)](DMF)(2)} (1; DMF = dimethylformamide) possesses three-dimensional microporosity as shown by X-ray diffraction and confirmed by CO2 and N-2 sorption studies. Compound 1 is composed of one-dimensional columns of tetrahedral Zn ions with homoleptic phosphonate coordination. This infinite building unit enables a robust and porous yet still crystalline material.
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